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S321 Stainless Steel

2025-03-11

S321 Stainless Steel

  1. Equivalent Standard Grades: Corresponds to Chinese grade 1Cr18Ni9Ti, U.S. grades 321, S32100, TP321, and Japanese grade SUS321.

  2. Material Properties
    2.1 Chemical Composition:

    • Carbon (C) ≤ 0.08%, Silicon (Si) ≤ 1.00%, Manganese (Mn) ≤ 2.00%, Sulfur (S) ≤ 0.030%, Phosphorus (P) ≤ 0.035%, Chromium (Cr): 17.00–19.00%, Nickel (Ni): 9.00–12.00%, Titanium (Ti) ≥ 5×C%.

    • The addition of Ti enhances resistance to intergranular corrosion but makes it unsuitable for decorative components.
      2.2 Corrosion Resistance:

    • Exhibits good corrosion resistance in organic and inorganic acids of varying concentrations and temperatures, particularly in oxidizing media.

    • Prolonged heating in temperature ranges prone to chromium carbide formation may degrade corrosion resistance in harsh environments.

    • Generally comparable to S347 in most environments but slightly inferior to annealed S347 in strongly oxidizing conditions.

  3. Mechanical Properties:

    • Tensile strength (σb) ≥ 520 MPa, Yield strength (σ0.2) ≥ 205 MPa, Elongation (δ5) ≥ 40%, Reduction of area (ψ) ≥ 50%, Hardness ≤ 187 HB, ≤ 90 HRB, ≤ 200 HV.

    • Offers better ductility and stress rupture resistance than 304 stainless steel at elevated temperatures.

  4. Weldability:

    • Good weldability. Ti addition suppresses chromium carbide formation during welding, reducing intergranular corrosion risks.

    • Requires controlled welding parameters (current, voltage, speed). Common methods include TIG and manual arc welding.

  5. Fabrication:

    • Suitable for cold/hot working. Cold working may require intermediate annealing due to significant work-hardening. Hot working temperature: 1000–1150°C.

  6. Applications:

    • Structural engineering (beams, bridges, transmission towers), industrial equipment (furnaces, reactors, pipelines), and high-temperature components (427–816°C), such as aircraft engine parts.

  7. Post-Weld Heat Treatment:

    • Solution treatment (920–1150°C rapid cooling) is recommended for high-temperature or high-stress applications. Stabilization treatment (850–930°C) may be specified.

  8. Non-Destructive Testing (NDT):

    • Ultrasonic and radiographic testing for internal defects. Fluorescent magnetic particle testing (enhanced sensitivity for magnetic zones) and penetrant testing for surface defects.

S347 Stainless Steel

  1. Equivalent Standard Grades: 347, S34700, 0Cr18Ni11Nb.

  2. Material Properties
    2.1 Chemical Composition:

    • Carbon (C) ≤ 0.08%, Manganese (Mn) ≤ 2.00%, Nickel (Ni): 9.00–13.00%, Silicon (Si) ≤ 1.00%, Phosphorus (P) ≤ 0.045%, Sulfur (S) ≤ 0.030%, Niobium (Nb) ≥ 10×C%, Chromium (Cr): 17.00–19.00%.

    • Nb addition improves resistance to intergranular corrosion.
      2.2 Corrosion Resistance:

    • Excellent resistance in acids, alkalis, and salts, with oxidation resistance up to 800°C.

    • Similar to S321 in most environments but slightly superior in aqueous and low-temperature conditions.

    • Designed for high-temperature applications requiring strong anti-sensitization to prevent intergranular corrosion.

  3. Mechanical Properties:

    • Solution-treated: Yield strength ≥ 206 MPa, Tensile strength ≥ 520 MPa, Elongation ≥ 40%, Hardness ≤ 187 HB.

    • Superior high-temperature stress rupture and creep resistance compared to 304 stainless steel.

  4. Weldability:

    • Good weldability (TIG, submerged arc welding). Nb minimizes intergranular corrosion, but excessive heat input must be avoided.

  5. Fabrication:

    • Similar to S321. Cold working requires attention to work-hardening; hot working temperature: 1050–1200°C.

  6. Applications:

    • Aerospace, power generation, chemical/petrochemical industries. Common in high-temperature equipment (boilers, heat exchangers).

  7. Post-Weld Heat Treatment:

    • Solution treatment is standard. Stabilization may be added for specific requirements.

  8. NDT:

    • Similar to S321. Fluorescent magnetic particle and penetrant testing for surface defects.

Key Differences & Selection Guidelines

  • Sensitization Resistance: S347 (with Nb) outperforms S321 (with Ti) in post-weld and high-temperature anti-corrosion.

  • Fabrication: S321’s Ti increases cold-working difficulty; S347’s Nb has less impact on workability.

  • Cost: S347 is more expensive due to Nb scarcity.

  • Summary:

    • S347: Preferred for long-term high-temperature stability and weld reliability (e.g., boilers, aerospace).

    • S321: Cost-effective for moderate/low-temperature applications (e.g., structural components, pipelines).